Dew Point Prediction by Lower Flash Points of Binary Mixtures 


Vol. 32,  No. 6, pp. 34-39, Dec.  2017
10.14346/JKOSOS.2017.32.6.34


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  Abstract

Vapor-liquid equilibrium calculation is required to properly design and operation of distillation process. The general calculation method is to use binary interaction parameter. Lower flash points of cyclohexanol+aniline and cyclohexanol+cyclohexanone were measured by using Seta-flash closed cup apparatus. The measured flash points were compared with those calculated by the method based on Raoult’s law and the optimization method using Wilson equation. The absolute average errors(A.A.E.) of the results calculated by Raout's law are 0.25℃ and 1.07℃ for yclohexanol+aniline and cyclohexanol+cyclohexanone, respectively. The absolute average errors of the results calculated by the optimization method are 0.22℃ and 0.65℃ for cyclohexanol+aniline and cyclohexanol+cyclohexanone, respectively. As can be seen from A.A.E., the calculated values based on the optimization method were found to be better than those based on the Raoult's law. The binary interaction parameters calculated by the optimization method are used to predict the dew points of cyclohexanol+aniline and cyclohexanol+cyclohexanone. The A.A.E. for these mixtures show that there is an acceptable agreement between experimental and calculated dew poins.

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  Cite this article

[IEEE Style]

하동명 and 이성진, "Dew Point Prediction by Lower Flash Points of Binary Mixtures," Journal of the Korean Society of Safety, vol. 32, no. 6, pp. 34-39, 2017. DOI: 10.14346/JKOSOS.2017.32.6.34.

[ACM Style]

하동명 and 이성진. 2017. Dew Point Prediction by Lower Flash Points of Binary Mixtures. Journal of the Korean Society of Safety, 32, 6, (2017), 34-39. DOI: 10.14346/JKOSOS.2017.32.6.34.