Development of Furan-Based Biomass Monomer and Its Utilization for Polyesters 


Vol. 61,  No. 6, pp. 324-329, Dec.  2024
10.12772/TSE.2024.61.324


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  Abstract

The tetrahydrofuran-3,4-diol (THF-diol) monomer was synthesized from erythritol biomass, and its potential for use in polyesters was investigated through a simple copolymerization with hexanediol and succinic acid. THF-diol monomer could be synthesized in one step from the inexpensive meso-erythritol, offering significant advantages in terms of cost and synthetic simplicity. However, the two hydroxyl groups are positioned too closely, leading to steric hindrance during polymerization and preventing effective polymerization. Despite this, the glass transition temperature gradually improved due to the increase in bulky cyclic ring groups within the polymer backbone, and the thermal stability remained sufficiently high. Polyesters containing THF-diol can be easily adjusted in terms of their physical and thermal properties, suggesting great potential in polymer synthesis.

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  Cite this article

[IEEE Style]

신. 철, 문예원, 정인환, "Development of Furan-Based Biomass Monomer and Its Utilization for Polyesters," Textile Science and Engineering, vol. 61, no. 6, pp. 324-329, 2024. DOI: 10.12772/TSE.2024.61.324.

[ACM Style]

신 철, 문예원, and 정인환. 2024. Development of Furan-Based Biomass Monomer and Its Utilization for Polyesters. Textile Science and Engineering, 61, 6, (2024), 324-329. DOI: 10.12772/TSE.2024.61.324.

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pISSN : 1225 - 1089
eISSN : 2288 - 6419

한국연구재단 우수등재학술지 유지 (2022년)