Synthesis of Copolymers from Acrylate Main Monomer and the Effect of Monomer Structure on Thermal Stability and Molecular Weight 


Vol. 60,  No. 4, pp. 242-248, Aug.  2023
10.12772/TSE.2023.60.242


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  Abstract

In this study, it was studied the relationship between the chemical structures of acrylate monomers and their thermal stability. To prepare the co-polymers based on acrylate monomer, emulsion polymerization was performed using with an initiator of AIBN (azobisisobutyronitrile). The thermal stability of the prepared copolymers was evaluated as a weight reduction rate by a thermogravimetric analyzer (TGA), and the molecular weight distribution of synthesized copolymers was analyzed by using a gel permeation chromatography (GPC). The hydrogen bond length and charge distribution caused by intermolecular interactions were simulated. The copolymerization of n-butyl acrylate and 2-chloroethyl vinyl ether resulted in a weight reduction of 0.41%, and an average molecular weight of 1,108,000.

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  Cite this article

[IEEE Style]

S. Lee, Y. Lee, J. Cheon, J. Choi, "Synthesis of Copolymers from Acrylate Main Monomer and the Effect of Monomer Structure on Thermal Stability and Molecular Weight," Textile Science and Engineering, vol. 60, no. 4, pp. 242-248, 2023. DOI: 10.12772/TSE.2023.60.242.

[ACM Style]

Shin-Jin Lee, Yoon-Gu Lee, Ji-Yeon Cheon, and Jae-Hong Choi. 2023. Synthesis of Copolymers from Acrylate Main Monomer and the Effect of Monomer Structure on Thermal Stability and Molecular Weight. Textile Science and Engineering, 60, 4, (2023), 242-248. DOI: 10.12772/TSE.2023.60.242.

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pISSN : 1225 - 1089
eISSN : 2288 - 6419

한국연구재단 우수등재학술지 유지 (2022년)