The Synergistic Effect of Organic Phosphorous/慣-Zirconium Phosphate on Flame-Retardant Poly(lactic acid) Fiber 


Vol. 19,  No. 4, pp. 812-820, Apr.  2018
10.1007/s12221-018-7828-5


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  Abstract

The flame-retardant poly(lactic acid) (FR-PLA) fibers with different contents of modified 慣-zirconium phosphate (慣-ZrP) and polysulfonyldiphenylene phenyl phosphonate (OP) were prepared by melt spinning. The organic modification of 慣-ZrP was characterized by Fourier transform infrared spectroscopy, wide angle X-ray diffraction, and thermo gravimetric analysis. The limiting oxygen index, vertical burning test, and cone calorimeter test were used to investigate the synergistic effect of OP/慣-ZrP on flame-retardant property of FR-PLA, the test results suggested that the combustion of PLA fibers was efficiently inhibited by OP/慣-ZrP. The results of scanning electron microscopy, Raman spectrum, and X-ray photoelectron spectroscopy indicated that the flame-retardant mechanism of OP/慣-ZrP mainly depended on condensed phase. The tensile strength and morphology of FR-PLA fibers with OP/慣-ZrP were better than those of fibers treated only with OP, demonstrating that 慣-ZrP could significantly improve the mechanical property of FR-PLA fibers.

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  Cite this article

[IEEE Style]

S. Yu, H. Xiang, J. Zhou, Z. Zhou, M. Zhu, "The Synergistic Effect of Organic Phosphorous/慣-Zirconium Phosphate on Flame-Retardant Poly(lactic acid) Fiber," Fibers and Polymers, vol. 19, no. 4, pp. 812-820, 2018. DOI: 10.1007/s12221-018-7828-5.

[ACM Style]

Senlong Yu, Hengxue Xiang, Jialiang Zhou, Zhe Zhou, and Meifang Zhu. 2018. The Synergistic Effect of Organic Phosphorous/慣-Zirconium Phosphate on Flame-Retardant Poly(lactic acid) Fiber. Fibers and Polymers, 19, 4, (2018), 812-820. DOI: 10.1007/s12221-018-7828-5.