A Comparative Study of Ni (II) Removal from Aqueous Solutions on Ca-Alginate Beads and Alginate-Impregnated Hemp Fibers 


Vol. 22,  No. 1, pp. 9-18, Jan.  2021
10.1007/s12221-021-9814-6


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  Abstract

Ca-alginate particles (CA) and alginate-impregnated hemp fibers (AH) (both, as prepared, dried, and rehydrated) were used as adsorbents for removal of Ni (II) ions from water. Adsorption was examined in the batch system and experimentally obtained data were analyzed by both linear and nonlinear curve fitting using pseudo-first and pseudo-secondorder rate, as well as Langmuir, Freundlich, and Sips equations. The concentration of Ni (II) ions was measured by atomic absorption spectrophotometry, while the Fourier transform infrared spectroscopy was used for characterization of adsorbent surface, before and after the adsorption. Although all tested samples showed similar adsorption capacities of 12 mg/g, it was found that rehydration improves adsorption characteristics of AH and increases the removal efficiency above 90 %. Adsorption of Ni (II) ions can be sufficiently described by both kinetic models and Sips isotherm equation, and this relatively fast process presumably occurs through the mechanism of physisorption and ion-exchange. The obtained results proved that Ca-alginate particles and alginate-impregnated hemp fibers have good potential to reduce nickel concentrations in a costeffective and efficient manner.

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  Cite this article

[IEEE Style]

A. Zduji훶, K. Trivunac, B. Peji훶, M. Vuk훾evi훶, M. Kosti훶, M. Milivojevi훶, "A Comparative Study of Ni (II) Removal from Aqueous Solutions on Ca-Alginate Beads and Alginate-Impregnated Hemp Fibers," Fibers and Polymers, vol. 22, no. 1, pp. 9-18, 2021. DOI: 10.1007/s12221-021-9814-6.

[ACM Style]

Aleksandar Zduji훶, Katarina Trivunac, Biljana Peji훶, Marija Vuk훾evi훶, Mirjana Kosti훶, and Milan Milivojevi훶. 2021. A Comparative Study of Ni (II) Removal from Aqueous Solutions on Ca-Alginate Beads and Alginate-Impregnated Hemp Fibers. Fibers and Polymers, 22, 1, (2021), 9-18. DOI: 10.1007/s12221-021-9814-6.

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