Successive Chemical Modification of Poly(acrylonitrile) Fibers with Glycidyl Methacrylate and Poly(p-phenylenediamine)/Ag Particles for an Efficient Antibacterial Activity 


Vol. 23,  No. 3, pp. 589-600, Mar.  2022
10.1007/s12221-022-3099-2


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  Abstract

One of the most industrially-prominent fibers, polyacrylonitrile (PAN), was chemically modified with the two specific steps to gain new functional groups that enable the surface chemically attractive. First, the chemically-susceptible epoxy groups were introduced to the PAN through graft copolymerization of glycidyl methacrylate using benzoyl peroxide (Bz2O2) as an initiator. Secondly, the surface of GMA grafted-PAN fibers (PAN-g-GMA) was decorated by the poly(pphenylenediamine) (PFDA) and Ag nanoparticles through the in-situ oxidative polymerization of p-phenylenediamine (p- FDA) using AgNO3. The changes in the PAN fiber's weights were monitored by changing the experimental conditions such as Bz2O2 and GMA concentrations, polymerization temperature-time, and AgNO3/p-FDA mol ratio. The usage of 5

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  Cite this article

[IEEE Style]

N. S. Ero휓lu, M. K. Edo휓an, M. Karak캇힊la, M. Sa챌ak, "Successive Chemical Modification of Poly(acrylonitrile) Fibers with Glycidyl Methacrylate and Poly(p-phenylenediamine)/Ag Particles for an Efficient Antibacterial Activity," Fibers and Polymers, vol. 23, no. 3, pp. 589-600, 2022. DOI: 10.1007/s12221-022-3099-2.

[ACM Style]

Nihan Seven Ero휓lu, Meryem Kalkan Edo휓an, Meral Karak캇힊la, and Mehmet Sa챌ak. 2022. Successive Chemical Modification of Poly(acrylonitrile) Fibers with Glycidyl Methacrylate and Poly(p-phenylenediamine)/Ag Particles for an Efficient Antibacterial Activity. Fibers and Polymers, 23, 3, (2022), 589-600. DOI: 10.1007/s12221-022-3099-2.