Fe(II)-Anchored Cotton Fabric for Heterogeneous Fenton Degradation of Rhodamine B Dye 


Vol. 23,  No. 10, pp. 2809-2819, Oct.  2022
10.1007/s12221-022-4104-5


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  Abstract

The ferric ions sludge produced during pollutants degradation was an obstacle for large scale application of Fenton oxidation technology. Herein, we reported a facile method using 2,2,6,6-tetramethylpiperidine-1-oxygen radical (TEMPO)- oxidized cotton fabric as a substrate for anchoring Fe(II) ions to produce Fe(II)-anchored cotton fabric. The formation of Fe(II)-anchored cotton fabric was confirmed using EDS analysis and FTIR measurement. Bath experiments indicated that Fe(II)-anchored cotton fabric could Fenton oxidize rhodamine B (RhB) dye in a high efficient rate (95.9 %) within 60 min without second pollution. Fe(II)-anchored cotton could be reused without any physical/chemical treatment and its decolorization efficiency was retained at 89.9 % even after the third cycle. Moreover, the decolorization behavior of Fe(II)- anchored cotton fabric for the RhB solution was affected by H2O2 dosage, Fe(II) ion content, and inorganic salts. Kinetic study indicated that the RhB decolorization process fits a pseudo-first order well and the sorption isotherm assessment revealed that the reactive sorption of RhB dye on Fe(II)-anchored cotton fabric fits the Freundlich model.

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  Cite this article

[IEEE Style]

Y. Yang, H. Chen, R. Zhang, J. Huang, Z. Bai, S. Xiao, "Fe(II)-Anchored Cotton Fabric for Heterogeneous Fenton Degradation of Rhodamine B Dye," Fibers and Polymers, vol. 23, no. 10, pp. 2809-2819, 2022. DOI: 10.1007/s12221-022-4104-5.

[ACM Style]

Yuhui Yang, Hongbin Chen, Ruquan Zhang, Jingjing Huang, Zhikui Bai, and Shili Xiao. 2022. Fe(II)-Anchored Cotton Fabric for Heterogeneous Fenton Degradation of Rhodamine B Dye. Fibers and Polymers, 23, 10, (2022), 2809-2819. DOI: 10.1007/s12221-022-4104-5.