Poly(ethylene glycol)-Templated Dyeing of Natural Phenol on Silk Fabric via Horseradish Peroxidase-Catalyzed 


Vol. 23,  No. 12, pp. 3482-3492, Dec.  2022
10.1007/s12221-022-4803-y


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  Abstract

The use of natural plants for dyeing is a new green approach in the textile industry using eco-friendly, renewable, and non-toxic reductants for dyeing fabric. Recently, various templates have been reported to enhance the polymerization of natural phenols. In this paper, ferulic acid (FA) was synthesized using a new approach and arranged on poly(ethylene glycol) (PEG) templates using horseradish peroxide (HRP)-catalyzed oxidative polymerization. The polymerization mechanism was studied in detail using high-performance liquid chromatography-electrospray ionization mass spectrometry (HPLC-ESI-MS) analysis. In addition, the template effect of PEG on 13 natural phenols was also investigated. Upon analyzing the color depth, the K/S value of the silk fabric dyed using PEG as a template was significantly higher than that in the absence of PEG. The higher color depth of the poly(ferulic acid)/PEG-treated silk fabrics further validated the important role of PEG as a template. This study presents an environmentally friendly method for dyeing silk fabric under mild conditions and the polymerization mechanism. Compared to chemical polymerization reactions, this enzyme (HRP)-based synthesis is more environmentally friendly due to its milder reaction conditions.

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  Cite this article

[IEEE Style]

N. Baek, X. Fan, L. Dai, L. Zhang, J. Yuan, "Poly(ethylene glycol)-Templated Dyeing of Natural Phenol on Silk Fabric via Horseradish Peroxidase-Catalyzed," Fibers and Polymers, vol. 23, no. 12, pp. 3482-3492, 2022. DOI: 10.1007/s12221-022-4803-y.

[ACM Style]

Na-won Baek, Xue-rong Fan, Li Dai, Lin Zhang, and Jiu-gang Yuan. 2022. Poly(ethylene glycol)-Templated Dyeing of Natural Phenol on Silk Fabric via Horseradish Peroxidase-Catalyzed. Fibers and Polymers, 23, 12, (2022), 3482-3492. DOI: 10.1007/s12221-022-4803-y.

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pISSN : 1229 - 9197
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