친환경 고분자 소재화를 위한 셀룰로스-리그닌 기반 가소화 기술 동향

Cellulose and lignin are abundant biomass resources, but their low processability and flexibility limit their use as thermoplastic materials. This review aims to address these challenges by examining the structural characteristics of cellulose and lignin and exploring various chemical and physical plasticization strategies. For cellulose, chemical modifications such as acetylation, esterification, and carboxymethylation can reduce hydrogen bonding and enhance flexibility. Additionally, plasticizers like glycerol, ionic liquids (ILs), and deep eutectic solvents (DES) further improve chain mobility. In the case of lignin, strategies such as alkylation, acetylation, and copolymerization with polyesters or polyurethanes have been investigated to lower the glass transition temperature and achieve thermoplasticity. By combining cellulose and lignin, we can create functional composites that exhibit enhanced mechanical properties, thermal stability, and biodegradability, especially when employing compatibilizers to modify interfacial properties. Applications of these plasticized materials include thermoplastic starch (TPS) and poly(lactic acid) (PLA) composites, which show promising performance. However, commercialization still faces technical and economic challenges, such as raw material heterogeneity, the need for ecofriendly processing, property optimization, and cost reduction. Future directions include designing ionic polymers and multifunctional nanocomposites to enhance performance and scalability. Collectively, cellulose and lignin have great potential as sustainable thermoplastic alternatives.

통계

2022년 11월부터 누적 집계
동일한 세션일 때 여러 번 접속해도 한 번만 카운트됩니다. 그래프 위에 마우스를 올리면 자세한 수치를 확인하실 수 있습니다.

논문 참조

[IEEE Style]

권제훈, 황동기, 유경철, 이가희, 구준모, 이승구, "Cellulose-Lignin Based Plasticizing Methods for Eco-friendly Plastics," Textile Science and Engineering, vol. 62, no. 4, pp. 183-199, 2025. DOI: 10.12772/TSE.2025.62.183.

[ACM Style]

권제훈, 황동기, 유경철, 이가희, 구준모, and 이승구. 2025. Cellulose-Lignin Based Plasticizing Methods for Eco-friendly Plastics. Textile Science and Engineering, 62, 4, (2025), 183-199. DOI: 10.12772/TSE.2025.62.183.

친환경 고분자 소재화를 위한 셀룰로스-리그닌 기반 가소화 기술 동향

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